Ultrafast One-Photon (232 vs 266 nm) Bond-Selective Photochemistry of Bromoiodomethane (CH2BrI) in Solution
Department of Chemistry, Center for Photochemical Sciences, Bowling Green State University, Bowling Green, OH, USA
Ultrafast broadband transient absorption spectra measured from the deep-ultraviolet to the near-infrared region following single-photon excitation of bromoiodomethane in acetonitrile at different wavelengths manifest chromophore -selective structural rearrangement and carbon-halogen bond dissociation in solution.
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