EPJ Web of Conferences
Volume 18, 2011Chemistry in Astrophysical Media, AstrOHP 2010
|Number of page(s)||17|
|Section||Heterogeneous Chemistry in Astrophysical Media|
|Published online||27 January 2012|
Theoretical approaches to nucleation in the gas phase. With a glimpse at experiments and dust formation in astrophysics
1 Institut des Sciences Moléculaires d’Orsay, CNRS UMR 8214, Université Paris Sud 11, Bât. 210, 91405 Orsay, France
2 LASIM, CNRS and Université Claude Bernard Lyon I, 43 Bd. du 11 Novembre 1918, 69622 Villeurbanne Cedex, France
An overview of the physics of homogeneous nucleation is presented, focusing on the main theoretical approaches that are currently available. We review the microscopic assumptions behind classical nucleation theory, as well as several improvements with various degrees of empiricism. The increasing role played by molecular simulations in testing and correcting nucleation theories is discussed. Typical laboratory experiments on homogeneous nucleation are also reviewed, emphasizing how experimental observables can be compared with theoretical predictions. Finally, the more specific challenges of nucleation in astrophysical media are discussed.
© Owned by the authors, published by EDP Sciences, 2011
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