Ultrafine Sm-Fe-N Particles Prepared by Planetary Ball Milling

Department of Physics and Astronomy, University of DE, Newark, DE, USA

Abstract

Ultrafine magnetically hard particles are needed for the bottom­up fabrication of anisotropic exchanged­coupled permanent magnets. In this study we have chosen Sm₂Fe₁₇N_x because of its high anisotropy field and large saturation magnetization. A multi­stage planetary ball milling process was used. The key is to find the right balance of energy used to mill the precursor particles; it must be high enough to break the particles and reduce their size but, not so high as to destroy the crystal structure of the nanoparticles that would lead to deterioration of the magnetic properties. First the coarse powders were subjected to a wet milling with 2.0 mm diameter media. In each subsequent stage the media size was reduced to maintain the milling balance. Using such a process produced particles in a size range from 100 - 800 nm with a coercivity as high as 10 kOe at room temperature.