EPJ Web of Conferences
Volume 41, 2013XVIIIth International Conference on Ultrafast Phenomena
|Number of page(s)||3|
|Section||Atomic, Molecular and Optical Science – Gas Phase|
|Published online||13 March 2013|
Dynamic Stark shift of the 3R1 Rydberg state of CH3I
1 Departamento de Química Física. Facultad de Ciencias Químicas. Universidad Complutense de Madrid, 28040 Madrid, Spain
2 Instituto Química Física Rocasolano, CSIC, C/ Serrano, 119, 28006 Madrid, Spain
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Stark shift of the 3R1 Rydberg state of CH3I is measured for different Stark field intensities. Photodissociation products, generated after predissociation of the state, were detected when the molecules were excited with photons resonant with the energy difference between the ground and the shifted 3R1 state, allowing the shift to be quantified. Qualitative agreement has been found with a 1D model.
© Owned by the authors, published by EDP Sciences, 2013
This is an Open Access article distributed under the terms of the Creative Commons Attribution License 2.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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