EPJ Web of Conferences
Volume 41, 2013XVIIIth International Conference on Ultrafast Phenomena
|Number of page(s)||3|
|Section||Chemistry – Condensed Phase|
|Published online||13 March 2013|
Molecular wave packet dynamics decelerated by solvent environment: A theoretical approach
1 Department Chemie, LMU München, Butenandtstr. 11, D-81377 München, Germany
2 LS für BioMolekulare Optik, LMU München, Oettingenstr. 67, D-80538 München, Germany
3 present address: Department of Information Technology, Uppsala Universitet, SE-751 05 Uppsala, Sweden
4 present address: Department of Chemistry, University of California, Irvine, California 92697-2025, USA
We present a new dynamic continuum ansatz to describe the frictional force exerted on moving wave packets in a solvent cage. The solvent interferes on the femtosecond time scale, but decides the reaction outcome.
© Owned by the authors, published by EDP Sciences, 2013
This is an Open Access article distributed under the terms of the Creative Commons Attribution License 2.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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