EPJ Web Conf.
Volume 132, 2017XXV-th Congress on Spectroscopy
|Number of page(s)||2|
|Published online||13 December 2016|
Spectral manifestation of substitution of out-of-plane ligands in metallophtalocyanines
1 B.I. Stepanov Institute of Physics, NAS of Belarus, Minsk, Belarus
2 Institute of Physical Chemistry, Polish Academy of Sciences, Warsaw, Poland
3 V.I.Vernadskii Institute of General and Inorganic Chemistry, NAS of Ukraine, Kyiv, Ukraine
* Corresponding author: email@example.com
Published online: 13 December 2016
In our study, we demonstrate the splitting effect of long-wavelength bands in absorption spectra (excitation of fluorescence) of the series of Zn(II), Ti(IV), Zr(IV) and Hf(IV) phthalocyanines at low temperatures. The effect has been explained by the shift of metal ion out of the plane of phthalocyanine macrocycle, the transformation of macrocycle to nonplanar “dome” conformation and additional loss the high symmetry of macrocycle.
© The Authors, published by EDP Sciences, 2017
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