EPJ Web Conf.
Volume 205, 2019XXI International Conference on Ultrafast Phenomena 2018 (UP 2018)
|Number of page(s)||3|
|Section||Field Driven and Spin Dynamics|
|Published online||16 April 2019|
Ultrafast spin crossover in a single crystal
1 Departments of Chemistry and Physics, University of Toronto, 80 St. George Street, Toronto, Ontario, M5S 3H6, Canada
2 Center for Free Electron Laser Science, Max Planck Institute for the Structure and Dynamics of Matter, Bld. 99, Luruper Chaussee 149, 22761 Hamburg, Germany
3 European XFEL GmbH, Holzkoppel 4, 22869 Schenefeld, Germany
* Corresponding author: email@example.com
Published online: 16 April 2019
Femtosecond spectroscopy and electron diffraction are used to characterize spin crossover in single crystal iron(II)-tris(bipyridine)-bis(hexafluorophosphate). The high-spin lifetime is reduced compared to in solution. Preliminary electron diffraction experiments show evidence of ultrafast Fe-N bond elongation associated with spin crossover and the subsequent molecular reorganization resulting from vibrational cooling.
© The Authors, published by EDP Sciences, 2019
This is an Open Access article distributed under the terms of the Creative Commons Attribution License 4.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Current usage metrics show cumulative count of Article Views (full-text article views including HTML views, PDF and ePub downloads, according to the available data) and Abstracts Views on Vision4Press platform.
Data correspond to usage on the plateform after 2015. The current usage metrics is available 48-96 hours after online publication and is updated daily on week days.
Initial download of the metrics may take a while.