EPJ Web Conf.
Volume 205, 2019XXI International Conference on Ultrafast Phenomena 2018 (UP 2018)
|Number of page(s)||3|
|Section||Ultrafast Photochemistry and Photosynthesis|
|Published online||16 April 2019|
Ultrafast proton transport in water-methanol mixtures
1 Max Born Institut für Nichtlineare Optik und Kurzzeitspektroskopie, 12489 Berlin, Germany
2 Martin-Luther-Universität Halle-Wittenberg, Institut für Chemie, 06120 Halle (Saale), Germany
Published online: 16 April 2019
Femtosecond UV/IR pump-probe experiments and ab initio molecular dynamics simulations of 7-hydroxyquinoline in water-methanol mixtures demonstrate an unexpectedly dominant OH-/CH3O- transport pathway but consistent with a solvent-dependent photoacidity free energy-reactivity correlation behaviour.
© The Authors, published by EDP Sciences, 2019
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