Raman Microscopy Identification of Secondary Spurious Phases in Molten GdSr₂RuCu₂O_8-δ Superconductor for Photonics and Plasmonic Applications

¹ CNR-ISASI SS Napoli, Napoli, ITALY
² CNR-IEOS Napoli, Napoli, ITALY
³ ENEA CR Casaccia, Santa Maria di Galeria (Roma), ITALY
⁴ Università di Salerno, Dipartimento di Fisica “E.R. Caianiello”, Fisciano (Salerno), ITALY
⁵ CNR-SPIN UOS Salerno, Fisciano (Salerno), ITALY
⁶ Università di Napoli “Federico II”, Dipartimento di Chimica, Napoli, ITALY
⁷ CNR-IOM HQ Trieste, Basovizza (Trieste), ITALY

^* Corresponding author: marcello.gombos@cnr.it

Published online: 31 October 2024

Abstract

Plasmonic and Photonics applications of superconducting materials, suggested at first by the necessity to minimize the dissipative losses of conventional metals in the high frequency ranges, are topics of growing interest in Optics. In this perspective, GdSr₂RuCu₂O_8-δ (Gd1212) Rutheno-Cuprate Superconductor presents very promising properties, showing both superconducting and magnetically ordered phases coexisting in the same cell. To investigate its features, the fabrication of macroscopic crystallographically oriented samples is necessary. The use of melt texturing techniques has shown to be among the most effective ways to achieve the best characteristics, although the fabrication of high-quality Gd1212 samples is intrinsically difficult.

To reach a better understanding of Gd1212 incongruent melting reaction, a series of bulk samples annealed at temperatures below and above the melting temperature was prepared. Raman Microscopy and Mapping performed on molten and re-solidified samples revealed the presence of different phases, corresponding to those identified in our previous studies. These observations were also confirmed by XRD, TGA-DTA, and SEM+EDS characterisations. Secondary phases formation showed a strong dependence on the temperature of the annealing treatments.

Susceptibility and magnetization measurements show both superconducting and magnetic transitions and a contribution of different spurious magnetic phases as suggested by EDS.