EPJ Web of Conferences
Volume 41, 2013XVIIIth International Conference on Ultrafast Phenomena
|Number of page(s)||3|
|Section||Chemistry – Condensed Phase|
|Published online||13 March 2013|
High spin ↔ low spin ultrafast excitation and relaxation of an isolated iron(II) complex.
1 University of Bordeaux, CNRS-UMR 5798, LOMA, 351 cours de la Libération, Talence 33405, France
2 CNRS, University of Bordeaux, ICMCB, 87 avenue du, Dr A. Schweitzer, Pessac, F-33608, France
Picosecond and femtosecond time resolved pump-probe experiments make it possible to study both the low spin (LS) to high spin (HS) and high spin to low spin excitation and relaxation processes in the same isolated iron(II) complex. We demonstrate that both LS → HS and HS → LS can be recorded by changing the pump wavelength and occur on the same time scale.
© Owned by the authors, published by EDP Sciences, 2013
This is an Open Access article distributed under the terms of the Creative Commons Attribution License 2.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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