EPJ Web of Conferences
Volume 41, 2013XVIIIth International Conference on Ultrafast Phenomena
|Number of page(s)||3|
|Section||Chemistry – Condensed Phase|
|Published online||13 March 2013|
Femtosecond UV-pump mid-IR probe spectroscopy of the ultrafast photodissociation of azide radicals from an azidoiron(III) complex
1 Max-Planck-Institut for biophysical Chemistry, Am Fassberg 11, 37077 Göttingen, Germany
2 Institute for Physical and Theoretical Chemistry, University of Bonn, Wegelerstraße 12, 53115 Bonn, Germany
a e-mail: firstname.lastname@example.org
The ultrafast photolysis of the cation complex [(cyclam-ac)FeN3]+ is studied by femtosecond spectroscopy with ultraviolet excitation and mid-infrared probing. Immediately after UV absorption, the excited complex undergoes internal conversion and azide dissociation within 2 ps. The subsequent vibrational relaxation in the electronic ground state and geminate recombination of the fragments take place on time scales of 13 and 20 ps, respectively.
© Owned by the authors, published by EDP Sciences, 2013
This is an Open Access article distributed under the terms of the Creative Commons Attribution License 2.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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