| Issue |
EPJ Web of Conferences
Volume 41, 2013
XVIIIth International Conference on Ultrafast Phenomena
|
|
|---|---|---|
| Article Number | 06001 | |
| Number of page(s) | 3 | |
| Section | Water, Hydrogen Bonding and Hydration | |
| DOI | https://doi.org/10.1051/epjconf/20134106001 | |
| Published online | 13 March 2013 | |
https://doi.org/10.1051/epjconf/20134106001
Femtosecond two-dimensional infrared spectroscopy of synthetic hydrogen-bonded wires: From homogeneous to inhomogeneous dynamics
Institute for Physical and Theoretical Chemistry, University of Bonn, Wegelerstraße 12, 53115 Bonn, Germany
a e-mail: p.voehringer@uni-bonn.de
Femtosecond two-dimensional infrared (2DIR) spectroscopy was carried out on stereo-selectively synthesized poly-alcohols featuring a quasi-linear array of hydrogen-bonds. From the 2DIR spectra pump-frequency-dependent vibrational lifetimes are extracted, which in turn reflect the strength of the coupling between the hydroxyls constituting the H-bonded chain. The line-broadening dynamics reflect uniquely the conformational control of the scaffold supporting the H-bond wire and the resulting structural flexibility of the hydrogen-bond network.
© Owned by the authors, published by EDP Sciences, 2013
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