Second harmonic generation from nano cavities milled in thin aluminum film

Institute of Nanotechnology and Advanced Materials (BINA), Chemistry department, Bar-Ilan University, 529000, Ramat-Gan, Israel.

^* Corresponding author: adi.salomon@biu.ac.il

Published online: 18 October 2023

Abstract

Second harmonic generation (SHG) is forbidden for centrosymmetric materials such metals. Yet, symmetry can be broken by introducing plasmonic nano-structures which lead to enhancement of the electromagnetic field at both the fundamental and the SH frequencies. Using non-linear microscopy, we experimentally demonstrate enhanced SHG from isosceles triangular cavities (~215 nm side length, 200 nm base) milled in thin aluminum film. Upon strong interaction between the cavities, they behave as a single unit and response in a coherent manner, i.e. SHG is observed from the coupled system. The hybridization between the cavities is not only dependent on the distance between them, but their spatial arrangement is found to be a crucial parameter. That is, the SHG efficiency can be enhanced upon different arrangement of the same cavities, holding the same distance between them. We characterize those cavities also by cathodoluminescence and show that the structure support plasmonic modes both at the fundamental and the SH frequencies.